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Refractory Metal TZM · heat-treated state

Refractory Metal TZM Vacuum Annealed

Properties of the Vacuum Annealed condition, compared with the other TZM tempers.

Choose when maximum dimensional stability and creep resistance above 1400 °C matter more than room-temperature strength; more brittle at RT because DBTT rises.

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What is TZM Vacuum Annealed?

TZM Vacuum Annealed is TZM heat treated to Vacuum Annealed — choose when maximum dimensional stability and creep resistance above 1400 °C matter more than room-temperature strength; more brittle at RT because DBTT rises. TZM Vacuum Annealed has a yield strength of 420 MPa (60.9 ksi) and a tensile strength of 560 MPa (81.2 ksi) — stronger than 65% of refractory metal grades. Elongation at break is 25% and the elastic modulus is 315 GPa (45.7 Msi). TZM Vacuum Annealed has a density of 10.22 g/cm³ (0.369 lb/in³), heavier than 67% of refractory metal grades. It melts at 2,617°C (4,743 °F). Stress Relieved is the default condition FabDigit quotes; Vacuum Annealed is available on request or by drawing note.

Advantages

  • Easy to machine — 50/100, better than 101% of refractory metal grades
  • High service temperature — 1,500°C (2,732 °F), better than 85% of refractory metal grades
  • Conducts heat well — 126 W/m·K (72.8 BTU/hr·ft·°F), better than 85% of refractory metal grades
  • High electrical conductivity — 30 % IACS, better than 84% of refractory metal grades
  • Stiff — 315 GPa (45.7 Msi), better than 76% of refractory metal grades

Limitations

  • Needs corrosion protection — 45/100, worse than 87% of refractory metal grades
  • Difficult to weld — 20/100, worse than 79% of refractory metal grades

TZM Vacuum Annealed properties

Typical room-temperature values for TZM Vacuum Annealed — 12 properties are specific to this condition; the rest are grade-level values shared by every TZM temper. Each bar shows where the value sits among the refractory metal grades in FabDigit's library — further right is higher.

Physical3

TZM Vacuum Annealed has a density of 10.22 g/cm³ (0.369 lb/in³), heavier than 67% of refractory metal grades. It melts at 2,617°C (4,743 °F).

Density10.22 g/cm³0.37 lb/in³
Melting Point (Solidus)2,617°C4,743 °F
Liquidus Temperature2,623°C4,753 °F

Mechanical16

TZM Vacuum Annealed has a yield strength of 420 MPa (60.9 ksi) and a tensile strength of 560 MPa (81.2 ksi) — stronger than 65% of refractory metal grades. Elongation at break is 25% and the elastic modulus is 315 GPa (45.7 Msi).

Elastic (Young's) Modulus315 GPa45.7 Msi
Shear Modulus122 GPa17.7 Msi
Bulk Modulus260 GPa37.7 Msi
Poisson's Ratio0.32
Tensile Strength (Ultimate)560 MPa81.2 ksi
Yield Strength (0.2% offset)420 MPa60.9 ksi
Elongation at Break25%
Reduction in Area55%
Compressive Strength800 MPa116 ksi
Shear Strength500 MPa72.5 ksi
Fatigue Strength (Endurance Limit)240 MPa34.8 ksi
Fracture Toughness (K_IC)20 MPa·√m18.2 ksi·√in
Charpy V-Notch Impact (RT)4 J3 ft·lbf
Hardness, Brinell255 HB
Hardness, Rockwell C12 HRC
Hardness, Vickers195 HV

Thermal6

TZM Vacuum Annealed is rated for continuous service to 1,500°C (2,732 °F). It conducts heat at 126 W/m·K (72.8 BTU/hr·ft·°F), better than 85% of refractory metal grades. Thermal expansion is 5.3 µm/m·K (2.94 µin/in·°F).

Thermal Conductivity126 W/m·K72.8 BTU/hr·ft·°F
Specific Heat Capacity272 J/kg·K0.06 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)5.3 µm/m·K2.9 µin/in·°F
Latent Heat of Fusion390 J/g168 BTU/lb
Max Service Temperature (continuous)1,500°C2,732 °F
Min Service Temperature20°C68 °F

Electrical3

TZM Vacuum Annealed conducts electricity at 30 % IACS, better than 84% of refractory metal grades.

Electrical Conductivity30 % IACS
Electrical Resistivity5.8×10⁻⁸ Ω·m2.28 µΩ·in
Magnetic Responsenon-magnetic

Chemical & Environmental3

Corrosion resistance is fair (45/100), worse than 87% of refractory metal grades.

Galvanic Potential (seawater, vs SCE)-0.2 V
Corrosion ResistanceFair45/100
Chemical Resistance SummaryExcellent in vacuum, hydrogen, inert gas, molten glass and many liquid metals (Li, Na, Bi, Zn); resists HCl, HF and non-oxidizing acids and molten alkali-free glass. Attacked by nitric acid, aqua regia, hot concentrated sulfuric acid, molten alkalis/nitrates and by oxygen — forms volatile MoO₃ above about 500 °C in air.

Sustainability4

Producing a kilogram of TZM Vacuum Annealed takes about 380 MJ of energy and emits 26 kg of CO₂ — less than 77% of refractory metal grades. Typical recycled content is 25%.

Embodied Energy (primary production)380 MJ/kg163,371 BTU/lb
Embodied Carbon (primary production)26 kg CO₂/kg
Embodied Water300 L/kg35.9 gal/lb
Typical Recycled Content25%

Manufacturability7

TZM Vacuum Annealed's machinability is fair (50/100, better than 101% of refractory metal grades); weldability poor (20/100); formability poor (20/100).

MachinabilityFair50/100
Machinability Rating (AISI 1212 = 100 %)40%
WeldabilityPoor20/100
Formability (cold)Poor20/100
Brazeability / SolderabilityGood65/100
PolishabilityVery good70/100
Anodizing Responsen/a — not anodized; oxidation protection is achieved with Si-Cr-Fe (silicide) or CVD/PVD coatings for air service above 500 °C

Values are nominal handbook figures for design screening. Certified mill or lot data ships with every FabDigit order on request.

Other TZM tempers and conditions

TZM is also supplied in 4 other conditions. The full side-by-side table is on the TZM overview.

Working with TZM Vacuum Annealed

Is TZM easy to machine?

Machines like a hard, abrasive cast iron — sharp positive-rake carbide or PCD tools, rigid setup, generous coolant, avoid dull edges that cause chipping and subsurface cracks; grinding and EDM work well.

Can TZM be welded?

Fusion welding (EB, laser, GTAW in chamber) recrystallizes and embrittles the joint — prefer vacuum brazing, mechanical fastening or friction/diffusion bonding for structural parts.

Can TZM be formed, bent or molded?

Form warm (200–500 °C, higher for recrystallized stock) to stay above the DBTT; generous bend radii, no sharp cold bends, and stress relieve at 900–1100 °C after heavy work.

What surface finishes work on TZM?

Cannot be anodized; use electropolishing or mechanical polish for clean vacuum surfaces and Si-Cr-Fe silicide, aluminide or CVD coatings when the part must see air above ~500 °C.

TZM chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
Ticarbide former, main strengthener0.4 – 0.550.5
Zr0.06 – 0.120.08
Cforms TiC/ZrC dispersoids0.01 – 0.040.03
O≤ 0.03
N≤ 0
Fe≤ 0.01
Ni≤ 0.01
Si≤ 0.01
Mobalance, ≥99.2 % with additionsbalance

TZM Vacuum Annealed — frequently asked

What is TZM Vacuum Annealed used for?

TZM Vacuum Annealed is typically used for rocket nozzles and thrust chamber inserts, hot-work extrusion and forging dies, furnace hot-zone structures and fixtures, die-casting core pins and shot sleeves, isothermal forging tooling and X-ray rotating anode substrates. In short: higher-strength molybdenum alloy.

What is the yield strength of TZM Vacuum Annealed?

TZM Vacuum Annealed has a typical yield strength of 420 MPa (60.9 ksi) and a tensile strength of 560 MPa (81.2 ksi) — stronger than 65% of refractory metal grades. Strength varies by condition: see the 5 listed tempers.

Is TZM Vacuum Annealed easy to machine?

Reasonably — machinability is rated fair (50/100, better than 101% of refractory metal grades). Machines like a hard, abrasive cast iron — sharp positive-rake carbide or PCD tools, rigid setup, generous coolant, avoid dull edges that cause chipping and subsurface cracks; grinding and EDM work well.

Can TZM Vacuum Annealed be welded?

Not readily — weldability is rated poor (20/100). Fusion welding (EB, laser, GTAW in chamber) recrystallizes and embrittles the joint — prefer vacuum brazing, mechanical fastening or friction/diffusion bonding for structural parts.

What surface finishes work on TZM Vacuum Annealed?

Cannot be anodized; use electropolishing or mechanical polish for clean vacuum surfaces and Si-Cr-Fe silicide, aluminide or CVD coatings when the part must see air above ~500 °C.

Can TZM Vacuum Annealed be formed, bent or molded?

Form warm (200–500 °C, higher for recrystallized stock) to stay above the DBTT; generous bend radii, no sharp cold bends, and stress relieve at 900–1100 °C after heavy work.

What is the maximum service temperature of TZM Vacuum Annealed?

TZM Vacuum Annealed is rated for continuous use to about 1,500°C (2,732 °F). Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

Can FabDigit make parts in TZM Vacuum Annealed?

Yes — TZM Vacuum Annealed is available for CNC machining and sheet metal with instant online pricing. Upload a STEP file to get a price and a DFM check.

Sources

  1. ASTM B387 — Molybdenum and Molybdenum Alloy Bar, Rod, and Wire (Type 364 TZM)ASTM International (2018)
  2. ASTM B386 — Molybdenum and Molybdenum Alloy Plate, Sheet, Strip, FoilASTM International (2018)
  3. TZM molybdenum alloy material propertiesPlansee SE (2023)
  4. ASM Handbook Vol. 2 — Properties of Refractory Metals and AlloysASM International (1990)
  5. Molybdenum and TZM technical dataH.C. Starck Solutions / Ed Fagan Inc. (2022)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.