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PTFE · matrix

PTFE Modified PTFE

Properties of the Modified PTFE condition, compared with the other PTFE grades.

Pick for permeation-tight linings, high-purity semiconductor fluid handling and thin welded/fused parts — finer structure, less cold flow and better weldability than standard PTFE.

What is PTFE Modified PTFE?

PTFE Modified PTFE is PTFE in the Modified PTFE condition — pick for permeation-tight linings, high-purity semiconductor fluid handling and thin welded/fused parts — finer structure, less cold flow and better weldability than standard PTFE. PTFE Modified PTFE has a yield strength of 12 MPa (1.74 ksi) and a tensile strength of 33 MPa (4.79 ksi) — weaker than 93% of polymer grades. Elongation at break is 430% and the elastic modulus is 0.5 GPa (0.0725 Msi). PTFE Modified PTFE has a density of 2.16 g/cm³ (0.078 lb/in³), heavier than 99% of polymer grades. Its glass-transition temperature is 126°C (259 °F). Virgin is the default condition FabDigit quotes; Modified PTFE is available on request or by drawing note.

Advantages

  • Good corrosion resistance — 98/100, better than 99% of polymer grades
  • High service temperature — 260°C (500 °F), better than 97% of polymer grades
  • Low moisture uptake — 0.01%, better than 97% of polymer grades
  • Good UV / weathering resistance — 95/100, better than 95% of polymer grades
  • Ductile — tolerates forming and impact — 430%, better than 87% of polymer grades

Limitations

  • Heavy — 2.16 g/cm³ (0.078 lb/in³), worse than 99% of polymer grades
  • High mold shrinkage — 4%, worse than 99% of polymer grades
  • Hard to polish — 20/100, worse than 95% of polymer grades
  • Low strength — 12 MPa (1.74 ksi), worse than 93% of polymer grades
  • High embodied carbon — 9.5 kg CO₂/kg, worse than 90% of polymer grades

PTFE Modified PTFE properties

Typical room-temperature values for PTFE Modified PTFE — 10 properties are specific to this condition; the rest are grade-level values shared by every PTFE grade. Each bar shows where the value sits among the polymer grades in FabDigit's library — further right is higher.

Physical6

PTFE Modified PTFE has a density of 2.16 g/cm³ (0.078 lb/in³), heavier than 99% of polymer grades. Its glass-transition temperature is 126°C (259 °F).

Density2.16 g/cm³0.08 lb/in³
Melting Temperature (Tm)325°C617 °F
Glass Transition (Tg)126°C259 °F
Water Absorption (24 h)0.01%
Water Absorption (Saturation)0.01%
Refractive Index1.35

Mechanical15

PTFE Modified PTFE has a yield strength of 12 MPa (1.74 ksi) and a tensile strength of 33 MPa (4.79 ksi) — weaker than 93% of polymer grades. Elongation at break is 430% and the elastic modulus is 0.5 GPa (0.0725 Msi).

Elastic (Young's) Modulus0.5 GPa0.07 Msi
Shear Modulus0.18 GPa0.03 Msi
Poisson's Ratio0.46
Tensile Strength (Ultimate)33 MPa4.8 ksi
Yield Strength (0.2% offset)12 MPa1.7 ksi
Elongation at Break430%
Compressive Strength16 MPa2.3 ksi
Compressive Modulus0.7 GPa0.1 Msi
Flexural Strength16 MPa2.3 ksi
Flexural Modulus0.5 GPa0.07 Msi
Shear Strength15 MPa2.2 ksi
Izod Impact, Notched160 J/m3 ft·lbf/in
Hardness, Shore A98 Shore A
Hardness, Shore D57 Shore D
Hardness, Rockwell R58 HRR

Thermal10

PTFE Modified PTFE is rated for continuous service to 260°C (500 °F). It conducts heat at 0.25 W/m·K (0.144 BTU/hr·ft·°F), better than 71% of polymer grades. Thermal expansion is 130 µm/m·K (72.2 µin/in·°F).

Thermal Conductivity0.25 W/m·K0.14 BTU/hr·ft·°F
Specific Heat Capacity1,000 J/kg·K0.24 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)130 µm/m·K72.2 µin/in·°F
Max Service Temperature (continuous)260°C500 °F
Min Service Temperature-200°C-328 °F
Heat Deflection Temp. @ 0.45 MPa121°C250 °F
Heat Deflection Temp. @ 1.8 MPa55°C131 °F
Flammability (UL 94)V-0
Limiting Oxygen Index95%
Max Service Temperature (short-term)300°C572 °F

Electrical7

PTFE Modified PTFE is an electrical insulator with a dielectric strength of 30 kV/mm (762 V/mil) and a resistivity of 1×10¹⁶ Ω·m.

Electrical Resistivity1×10¹⁶ Ω·m3.94×10²³ µΩ·in
Dielectric Strength30 kV/mm762 V/mil
Dielectric Constant (1 MHz)2.1
Dissipation Factor (1 MHz)2×10⁻⁴
Volume Resistivity1×10¹⁸ Ω·cm
Surface Resistivity1×10¹⁷ Ω
Comparative Tracking Index (CTI)600 V

Chemical & Environmental3

Corrosion resistance is excellent (98/100), better than 99% of polymer grades. UV resistance is excellent.

Corrosion ResistanceExcellent98/100
UV / Weathering ResistanceExcellent95/100
Chemical Resistance SummaryInert to virtually all acids, bases, solvents, fuels and oxidizers up to 260 °C; attacked only by molten alkali metals, elemental fluorine/chlorine trifluoride at elevated temperature and some hot fluorinated solvents (which cause swelling). Non-wetting, non-stick, zero moisture pickup; degrades above ~350 °C releasing corrosive HF/perfluoro gases.

Sustainability4

Producing a kilogram of PTFE Modified PTFE takes about 210 MJ of energy and emits 9.5 kg of CO₂ — more than 90% of polymer grades. Typical recycled content is 0%.

Embodied Energy (primary production)210 MJ/kg90,284 BTU/lb
Embodied Carbon (primary production)9.5 kg CO₂/kg
Embodied Water350 L/kg41.9 gal/lb
Typical Recycled Content0%

Manufacturability6

PTFE Modified PTFE's machinability is very good (80/100, better than 83% of polymer grades); weldability fair (40/100); formability very good (70/100).

MachinabilityVery good80/100
WeldabilityFair40/100
Formability (cold)Very good70/100
PolishabilityPoor20/100
Mold Shrinkage4%
Processing Melt Temperature (typ.)375°C707 °F

Values are nominal handbook figures for design screening. Certified mill or lot data ships with every FabDigit order on request.

Other PTFE grades and fills

PTFE is also supplied in 11 other conditions. The full side-by-side table is on the PTFE overview.

Working with PTFE Modified PTFE

Is PTFE easy to machine?

Machines easily with sharp positive-rake tools and high speed/low feed, but is soft and springy — expect elastic recovery, burr rollover and thermal-expansion-driven dimensional drift; stress-relieve stock and allow 24 h relaxation before final gauging.

Can PTFE be welded?

Cannot be solvent-bonded or conventionally hot-plate welded; joining is by fusion sintering above 360 °C under pressure, mechanical clamping, or adhesive bonding only after chemical/plasma or sodium-naphthalene surface etch.

Can PTFE be formed, bent or molded?

Not injection mouldable (melt viscosity ~10¹¹ Pa·s): granular resin is compression-preformed and free-sintered at 360–380 °C, paste resin is ram/paste extruded, and billets are skived into film or turned/machined; sintering shrinkage 3–6 % must be allowed.

What surface finishes work on PTFE?

Non-stick and non-paintable as moulded; use plasma, corona or sodium-etch pretreatment for printing/bonding, and expect no useful polish — surface finish is set by tooling and skiving quality.

PTFE chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
Felemental fluorine content by weight≈ 7676
Celemental carbon content by weight≈ 2424
glass fiberonly in glass-filled compounds0 – 250
carbon/graphiteonly in carbon/graphite-filled compounds0 – 250
bronze (CuSn)only in bronze-filled bearing compounds0 – 600
MoS2only in moly-filled compounds0 – 50
tetrafluoroethylene (–CF2–CF2–) repeat uhomopolymer; modified PTFE contains ≤1 % PPVE/HFP comonomer≥ 99 (balance)

PTFE Modified PTFE — frequently asked

What is PTFE Modified PTFE used for?

PTFE Modified PTFE is typically used for seals, gaskets and liners. In short: zero-friction; non-stick.

What is the yield strength of PTFE Modified PTFE?

PTFE Modified PTFE has a typical yield strength of 12 MPa (1.74 ksi) and a tensile strength of 33 MPa (4.79 ksi) — weaker than 93% of polymer grades. Strength varies by condition: see the 12 listed tempers.

Is PTFE Modified PTFE easy to machine?

Yes — machinability is rated very good (80/100, better than 83% of polymer grades). Machines easily with sharp positive-rake tools and high speed/low feed, but is soft and springy — expect elastic recovery, burr rollover and thermal-expansion-driven dimensional drift; stress-relieve stock and allow 24 h relaxation before final gauging.

Can PTFE Modified PTFE be welded?

With care — weldability is rated fair (40/100). Cannot be solvent-bonded or conventionally hot-plate welded; joining is by fusion sintering above 360 °C under pressure, mechanical clamping, or adhesive bonding only after chemical/plasma or sodium-naphthalene surface etch.

What surface finishes work on PTFE Modified PTFE?

Non-stick and non-paintable as moulded; use plasma, corona or sodium-etch pretreatment for printing/bonding, and expect no useful polish — surface finish is set by tooling and skiving quality.

Can PTFE Modified PTFE be formed, bent or molded?

Not injection mouldable (melt viscosity ~10¹¹ Pa·s): granular resin is compression-preformed and free-sintered at 360–380 °C, paste resin is ram/paste extruded, and billets are skived into film or turned/machined; sintering shrinkage 3–6 % must be allowed.

What is the maximum service temperature of PTFE Modified PTFE?

PTFE Modified PTFE is rated for continuous use to about 260°C (500 °F), and briefly to 300°C. Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

Can FabDigit make parts in PTFE Modified PTFE?

Yes — PTFE Modified PTFE is available for CNC machining, sheet metal and injection molding with instant online pricing. Upload a STEP file to get a price and a DFM check.

Sources

  1. ASTM D4894 / D4895 — PTFE Molding and Extrusion MaterialsASTM International (2022)
  2. ASTM D1710 — PTFE Rod, Heavy-Walled Tubing and Basic ShapesASTM International (2019)
  3. Engineered Materials Handbook Vol. 2: Engineering PlasticsASM International (1988)
  4. Teflon PTFE fluoropolymer resin properties handbookChemours/DuPont (2021)
  5. TECAFLON PTFE stock shapes datasheetEnsinger (2023)
  6. Dyneon PTFE / TFM modified PTFE product information3M Dyneon (2020)
  7. CAMPUS / plastics property datasets (fluoropolymers)CWFG / CAMPUS consortium (2024)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.