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PPS · grade · default condition

PPS Unfilled

Properties of the Unfilled condition, compared with the other PPS grades.

Pick when machining stock shapes, when isotropic shrinkage and low abrasiveness matter, or for thin dielectric parts; accept low stiffness and low impact.

What is PPS Unfilled?

PPS Unfilled is PPS in the Unfilled grade — pick when machining stock shapes, when isotropic shrinkage and low abrasiveness matter, or for thin dielectric parts; accept low stiffness and low impact. PPS Unfilled has a yield strength of 75 MPa (10.9 ksi) and a tensile strength of 78 MPa (11.3 ksi) — stronger than 83% of polymer grades. Elongation at break is 5% and the elastic modulus is 3.8 GPa (0.551 Msi). PPS Unfilled has a density of 1.35 g/cm³ (0.0488 lb/in³), heavier than 74% of polymer grades. Its glass-transition temperature is 88°C (190 °F).

Advantages

  • Good corrosion resistance — 92/100, better than 91% of polymer grades
  • High service temperature — 220°C (428 °F), better than 89% of polymer grades
  • Low moisture uptake — 0.03%, better than 88% of polymer grades
  • Stiff — 3.8 GPa (0.551 Msi), better than 84% of polymer grades
  • High strength — 75 MPa (10.9 ksi), better than 83% of polymer grades

Limitations

  • Limited formability — 15/100, worse than 80% of polymer grades

PPS Unfilled properties

Typical room-temperature values for PPS Unfilled — 13 properties are specific to this condition; the rest are grade-level values shared by every PPS grade. Each bar shows where the value sits among the polymer grades in FabDigit's library — further right is higher.

Physical5

PPS Unfilled has a density of 1.35 g/cm³ (0.0488 lb/in³), heavier than 74% of polymer grades. Its glass-transition temperature is 88°C (190 °F).

Density1.35 g/cm³0.05 lb/in³
Melting Temperature (Tm)280°C536 °F
Glass Transition (Tg)88°C190 °F
Water Absorption (24 h)0.03%
Water Absorption (Saturation)0.1%

Mechanical15

PPS Unfilled has a yield strength of 75 MPa (10.9 ksi) and a tensile strength of 78 MPa (11.3 ksi) — stronger than 83% of polymer grades. Elongation at break is 5% and the elastic modulus is 3.8 GPa (0.551 Msi).

Elastic (Young's) Modulus3.8 GPa0.55 Msi
Shear Modulus1.4 GPa0.2 Msi
Poisson's Ratio0.37
Tensile Strength (Ultimate)78 MPa11.3 ksi
Yield Strength (0.2% offset)75 MPa10.9 ksi
Elongation at Break5%
Compressive Strength120 MPa17.4 ksi
Compressive Modulus3.5 GPa0.51 Msi
Flexural Strength130 MPa18.9 ksi
Flexural Modulus3.9 GPa0.57 Msi
Shear Strength65 MPa9.4 ksi
Izod Impact, Notched25 J/m0.47 ft·lbf/in
Hardness, Shore D88 Shore D
Hardness, Rockwell M95 HRM
Hardness, Rockwell R123 HRR

Thermal10

PPS Unfilled is rated for continuous service to 220°C (428 °F). It conducts heat at 0.29 W/m·K (0.168 BTU/hr·ft·°F), better than 79% of polymer grades. Thermal expansion is 52 µm/m·K (28.9 µin/in·°F).

Thermal Conductivity0.29 W/m·K0.17 BTU/hr·ft·°F
Specific Heat Capacity1,000 J/kg·K0.24 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)52 µm/m·K28.9 µin/in·°F
Max Service Temperature (continuous)220°C428 °F
Min Service Temperature-40°C-40 °F
Heat Deflection Temp. @ 0.45 MPa240°C464 °F
Heat Deflection Temp. @ 1.8 MPa110°C230 °F
Flammability (UL 94)V-0 at 0.8 mm
Limiting Oxygen Index47%
Max Service Temperature (short-term)260°C500 °F

Electrical7

PPS Unfilled is an electrical insulator with a dielectric strength of 18 kV/mm (457.2 V/mil) and a resistivity of 1×10¹⁴ Ω·m.

Electrical Resistivity1×10¹⁴ Ω·m3.94×10²¹ µΩ·in
Dielectric Strength18 kV/mm457 V/mil
Dielectric Constant (1 MHz)3.1
Dissipation Factor (1 MHz)0.0013
Volume Resistivity1×10¹⁶ Ω·cm
Surface Resistivity1×10¹⁵ Ω
Comparative Tracking Index (CTI)175 V

Chemical & Environmental3

Corrosion resistance is excellent (92/100), better than 91% of polymer grades. UV resistance is fair.

Corrosion ResistanceExcellent92/100
UV / Weathering ResistanceFair35/100
Chemical Resistance SummaryNo known solvent below ~200 °C; excellent against acids, bases, fuels, hydraulic fluids, hot water/steam and automotive coolants. Attacked by hot concentrated oxidizing acids (nitric, chromic), hot chlorinated/aromatic solvents above 200 °C, and slowly degraded by strong sodium hypochlorite; unstabilized grades weather poorly in outdoor UV.

Sustainability4

Producing a kilogram of PPS Unfilled takes about 115 MJ of energy and emits 6.2 kg of CO₂ — more than 70% of polymer grades. Typical recycled content is 2%.

Embodied Energy (primary production)115 MJ/kg49,441 BTU/lb
Embodied Carbon (primary production)6.2 kg CO₂/kg
Embodied Water300 L/kg35.9 gal/lb
Typical Recycled Content2%

Manufacturability7

PPS Unfilled's machinability is good (60/100, better than 51% of polymer grades); weldability poor (30/100); formability poor (15/100).

MachinabilityGood60/100
WeldabilityPoor30/100
Formability (cold)Poor15/100
PolishabilityGood60/100
Mold Shrinkage1.2%
Processing Melt Temperature (typ.)320°C608 °F
Mold Temperature (typ.)140°C284 °F

Common Calculations5

Specific Strength (UTS / density)calculated58 kN·m/kg
Specific Stiffness (E / density)calculated2.8 MN·m/kg
Modulus of Resiliencecalculated740 kJ/m³
Thermal Diffusivitycalculated0.2 mm²/s
Thermal Shock Resistance Indexcalculated0

Values are nominal handbook figures for design screening. Certified mill or lot data ships with every FabDigit order on request.

Other PPS grades and fills

PPS is also supplied in 6 other conditions. The full side-by-side table is on the PPS overview.

Working with PPS Unfilled

Is PPS easy to machine?

Machines like a rigid, notch-sensitive thermoplastic — use sharp polished-flute carbide (PCD for glass/mineral-filled), high speed, light feed, air or mist cooling, and generous radii to avoid chipping.

Can PPS be welded?

No solvent bonding; join by ultrasonic, IR/hot-plate, laser or spin welding with matched fillers, or use epoxy adhesive after plasma/flame surface activation.

Can PPS be formed, bent or molded?

Dry 3 h at 150 °C, mold at 310–330 °C melt with 130–150 °C tool for full crystallinity; hardened, wear-resistant tool steel and vented gates are mandatory because glass-filled PPS is very abrasive and outgasses.

What surface finishes work on PPS?

Accepts pad printing, laser marking and vacuum metallizing; needs plasma or corona pre-treatment for paint adhesion, and unfilled grades polish to a semi-gloss but darken under UV.

PPS chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
glass fiberchopped E-glass in reinforced grades (GF30/GF40)0 – 400
mineral filler (CaCO3 / talc / wollastonused with glass in 65% total-filler grades0 – 450
carbon fiberconductive / high-stiffness grades0 – 300
PTFE / graphite / MoS2bearing and wear grades0 – 200
pigment, nucleant, coupling agent, heat typical additive package0 – 31
poly(1,4-phenylene sulfide) resinrepeat unit (C6H4S)n; polymerized from p-dichlorobenzene and sodium sulfide in NMPbalance

PPS Unfilled — frequently asked

What is PPS Unfilled used for?

PPS Unfilled is typically used for pump housings and impellers, valve seats, electrical connectors, coil bobbins, automotive under-hood components and airflow sensor housings. In short: strong chemical resistant.

What is the yield strength of PPS Unfilled?

PPS Unfilled has a typical yield strength of 75 MPa (10.9 ksi) and a tensile strength of 78 MPa (11.3 ksi) — stronger than 83% of polymer grades. Strength varies by condition: see the 7 listed tempers.

Is PPS Unfilled easy to machine?

Reasonably — machinability is rated good (60/100, better than 51% of polymer grades). Machines like a rigid, notch-sensitive thermoplastic — use sharp polished-flute carbide (PCD for glass/mineral-filled), high speed, light feed, air or mist cooling, and generous radii to avoid chipping.

Can PPS Unfilled be welded?

Not readily — weldability is rated poor (30/100). No solvent bonding; join by ultrasonic, IR/hot-plate, laser or spin welding with matched fillers, or use epoxy adhesive after plasma/flame surface activation.

What surface finishes work on PPS Unfilled?

Accepts pad printing, laser marking and vacuum metallizing; needs plasma or corona pre-treatment for paint adhesion, and unfilled grades polish to a semi-gloss but darken under UV.

Can PPS Unfilled be formed, bent or molded?

Dry 3 h at 150 °C, mold at 310–330 °C melt with 130–150 °C tool for full crystallinity; hardened, wear-resistant tool steel and vented gates are mandatory because glass-filled PPS is very abrasive and outgasses.

What is the maximum service temperature of PPS Unfilled?

PPS Unfilled is rated for continuous use to about 220°C (428 °F), and briefly to 260°C. Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

Can FabDigit make parts in PPS Unfilled?

Yes — PPS Unfilled is available for CNC machining, sheet metal and injection molding with instant online pricing. Upload a STEP file to get a price and a DFM check.

Sources

  1. Fortron PPS product and processing dataCelanese (2023)
  2. Ryton PPS compounds datasheetsSolvay Specialty Polymers (2022)
  3. Techtron / Techtron HPV PPS stock shapesMitsubishi Chemical Advanced Materials (2022)
  4. CAMPUS plastics database — PPS ISO 10350 datasetsCWFG / CAMPUS consortium (2023)
  5. Engineered Materials Handbook Vol. 2: Engineering PlasticsASM International (1988)
  6. ISO 527 / ISO 178 / ISO 75 / ASTM D256 / UL 94 test methodsISO / ASTM / UL (2019)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.